Photocurable Polymer Composition Based on Heat-Resistant Aromatic Polyamide for the Formation of Optical Elements by Two-Photon Polymerization

D. V. Ganin, D. S. Dudova, B. S. Shavkuta, O. S. Korkunova,B. Ch. Kholkhoev,P. S. Timashev,V. F. Burdukovskii,N. V. Minaev

OPTICS AND SPECTROSCOPY(2020)

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Abstract
Optical properties of a polymer composition based on heat-resistant aromatic polyamide are established and an approach to the formation of three-dimensional microoptical structures by two-photon polymerization on the base of this composition is developed. Formation of prototype polymer microoptical elements is proven in several regimes involving a two-photon polymerization system with the use of a laser source with a wavelength of 525 nm. The formed structures corresponded to the initial three-dimensional model, were optically transparent in the range from 450 nm, and preserved optical transparency after several cycles of heating up to 300°C.
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Key words
femtosecond laser radiation,multiphoton absorption,two-photon polymerization,3D-printing,photocurable polymeric compositions,heat-resistant aromatic polyamides
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