A continuous denitrification technology based on metal-organic framework without using ammonia
Journal of Cleaner Production(2021)
Abstract
Ammonia is widely used as the reductant in selective catalytic reduction of nitrogen oxide. However, ammonia slip results in environmental problems. In this work, a metal-organic framework was synthesized and applied in catalytic reduction of nitric oxide without using ammonia. As a result, the catalyst removed 100% of nitric oxide at 400 °C. A two-tube reactor was designed to ensure a continuous removal and catalyst regeneration at the same time. After the catalyst lost effect in nitric-oxide removal, it was easily regenerated by a simple hydrothermal method, and reached removal rates of 90.7–99.6% for several cycles. Mass spectrometer and electron paramagnetic resonance analysis revealed that nitric oxide was effectively reduced by carbon species, including carbons, ligands, derived gases, benzene free radical, and phenoxy-type radical. After calculation, 2.4 t of the catalyst could reduce 1400 Nm3 h−1 of flue gas, when nitric oxide concentration was 250 mg Nm−3 in it. Therefore, the investigated technology is a green and sustainable denitrification strategy, which would potentially substitute typical selective catalytic reduction of nitrogen oxide in the future.
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Key words
Metal organic framework,Regenerable,Continuous,Denitrification,Free radical
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