Synthesis Of Tempo Radical Decorated Hollow Porous Aromatic Frameworks For Selective Oxidation Of Alcohols
CHEMICAL COMMUNICATIONS(2021)
摘要
A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2 nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity.
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关键词
hollow porous aromatic frameworks,selective oxidation,tempo radical,alcohols
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