Mossbauer, Nuclear Forward Scattering, And Raman Spectroscopic Approaches In The Investigation Of Bioinduced Transformations Of Mixed-Valence Antimony Oxide
JOURNAL OF PHYSICAL CHEMISTRY A(2021)
Abstract
Mossbauer spectroscopy, nuclear forward scattering, and Raman spectroscopy were applied to study redox transformations of the synthesized mixed-valence (III/V) antimony oxide. The transformations were induced by a culture of a hyperthermophilic archaeon of the genus Pyrobaculum. The applied methods allowed us to reveal the minor decrease of ca. 11.0 +/- 1.2% of the antimony(V) content of the mixed-valence oxide with the concomitant increase of antimony(III). The method sensitivities for the quantitative assessment of the Sb(III/V) ratio have been considered.
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Key words
raman spectroscopic approaches,oxide,nuclear forward scattering,mixed-valence
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