Investigation of reactive gases and methane variability in the coastal boundary layer of the central Mediterranean basin

We present a characterization of reactive gases (RG: O-3, NO, NO2, SO2, CO) and methane (CH4) - variability in the central Mediterranean basin, analyzing in situ measurements at three new permanent WMO/GAW Observatories in Southern Italy: Capo Granitola - CGR (Sicily), Lamezia Terme - LMT (Calabria) and Lecce - ECO (Apulia). At all the measurement sites, a combination of the breeze wind system (especially at CGR and LMT), PBL dynamics, anthropogenic/natural emissions, and photochemistry lead the appearance of well-defined diurnal cycles for the observed RG. According to O-3/NOx variability, local emissions appeared to influence CGR and LMT (no NOx data were available for ECO during the period of study) in 4% and 20% of the hourly data, nearby sources in 39% and 40%, remote sources in 31% and 14%, while background O-3/NOx were observed in 26% of cases for both the stations. Most of the background O-3/NOx were observed during daytime, when offshore air masses usually affected the measurement sites. Local sources of CH4 at CGR can be related to biogenic (oxic) emissions from biomasses along the coastline, while emissions from live stocks can represent a local source of CH4 at LMT. Finally, we provide first hints about the export of O-3 from Sicily/Southern Italy to the Mediterranean Sea by comparing simultaneous observations at CGR and Lampedusa (LMP), a small island in the middle of the Strait of Sicily where a WMO/GAW Regional Station is located. In summer, O-3 increased by some 7 ppb for transport times lower than 48 h, while no statistical significant differences were observed for travel time longer than 48. This would suggest that photochemical O-3 production occurred within airmass travelling from CGR to LMP, but also that the - central Mediterranean MBL represents a O-3 sink for relatively aged air-masses.