Boric Acid-Fueled Atp Synthesis By Fof1 Atp Synthase Reconstituted In A Supramolecular Architecture

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2021)

引用 14|浏览20
暂无评分
摘要
Significant strides toward producing biochemical fuels have been achieved by mimicking natural oxidative and photosynthetic phosphorylation. Here, different from these strategies, we explore boric acid as a fuel for tuneable synthesis of energy-storing molecules in a cell-like supramolecular architecture. Specifically, a proton locked in boric acid is released in a modulated fashion by the choice of polyols. As a consequence, controlled proton gradients across the lipid membrane are established to drive ATP synthase embedded in the biomimetic architecture, which facilitates tuneable ATP production. This strategy paves a unique route to achieve highly efficient bioenergy conversion, holding broad applications in synthesis and devices that require biochemical fuels.
更多
查看译文
关键词
biochemical fuel, biomimetic architectures, biosynthesis, proton gradients, supramolecular assembly
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要