Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids

Corina Stoian,Marian Olaru,Theodor Cucuiet,Krisztina Kegyes,Alexandru Sava,Alexey Timoshkin,Ciprian Rat,Jens Beckmann

CHEMISTRY-A EUROPEAN JOURNAL（2021）

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摘要

Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6-(C6F5)(2)C6F3B(C6F5)(2) (1), 2,6-(C6F5)(2)C6F3B[3,5-(CF3)(2)C6H3] (2), 2,4,6-(C6F5)(3)C6H2B(C6F5)(2) (3), 2,4,6-(C6F5)(3)C6H2B[3,5-(CF3)(2)C6H3] (4) were developed. All boranes are water tolerant and according to the Gutmann-Beckett method, 1-3 display Lewis acidities larger than that of the prominent B(C6F5)(3).

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关键词

fluorinated compounds, kinetic stabilization, Lewis acids, terphenyl, water tolerant boranes

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