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Slow Magnetic Relaxation In Structurally Similar Mononuclear 8-Coordinate Fe(Ii) And Fe(Iii) Compounds

Qian-Qian Su,Qiong Yuan,Xiao-Fan Wu,Si-Huai Chen,Jing Xiang,Xin-Xin Jin,Li-Xin Wang,Bing-Wu Wang,Song Gao,Tai-Chu Lau

CHEMICAL COMMUNICATIONS（2021）

Cited 8|Views40
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Abstract
A pair of structurally-similar and stable 8-coordinate high-spin Fe(ii) and Fe(iii) compounds have been obtained. Both compounds exhibit field-induced slow magnetic relaxation behaviour. The Fe(iii) compound represents the first example of 8-coordinate Fe(iii) single-molecule magnets (SMM).
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magnetic relaxation,fe<scp>ii</scp>
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