DEGRADATION FEATURES OF ARCHAEOLOGICAL WOOD SURFACE TO DEEP INSIDE A CASE STUDY ON WOODEN BOARDS OF MARQUIS OF HAIHUN'S OUTER COFFIN

Although researches have been carried on the bio-chemical deterioration of archaeological wood, still the degradation of archaeological wood is so complicated to fully understand. One essential question is how archaeological wood of large volume would degrade from surface to deep inside and why. The recently unearthed outer coffin of Marquis of Haihun, buried for over 1800 years, gave us a great opportunity to investigate this question. The degradation features were analyzed with methods of optical microscopy, Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), viscosimetry, and determination of physical properties of wood. The results, including the microstructures of wood fibers, wood components, degree of polymerization and crystallinity of cellulose, and shrinkage of wood, unanimously show that the sapwood of the board is worst degraded, the surface layer of the heartwood is degraded to a higher extent than the inner part, and it tends to degrade more easily along the axial direction.