Stoichiometric assembly of [Sb(PCy)(3)](2)Li-6 center dot 6HNMe(2)center dot 2C(6)H(5)Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium

MA Beswick,JM Goodman,CN Harmer,AD Hopkins,MA Paver,PR Raithby,AEH Wheatley,DS Wright

CHEMICAL COMMUNICATIONS（1997）

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摘要

All of the Me2NH produced by the reaction of [Sb(NMe2)(3)] with CyP(H)Li(Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)(3)](2)Li-6 . 6HNMe(2) . 2C(6)H(5)Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)(3)](3-)}.

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