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C(sp(3))-C(sp(3)) bond formation via copper/Bronsted acid co-catalyzed C(sp(3))-H bond oxidative cross-dehydrogenative-coupling (CDC) of azaarenes

Fang-Fang Wang,Cui-Ping Luo,Guojun Deng,Luo Yang

GREEN CHEMISTRY（2014）

Cited 88|Views2
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Abstract
A copper/Bronsted acid dual-catalyst promoted oxidative cross-dehydrogenative-coupling of alkylazaarenes and tertiary amines for C(sp(3))-C(sp(3)) bond formation was developed. This method uses dioxygen as the terminal oxidant under mild reaction conditions and would provide a convenient benzylic C-H transformation of alkylazaarenes to biologically active pharmaceutics.
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Key words
azaarenes,bond formation,cheminform abstract,co-catalyzed,cross-dehydrogenative-coupling
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