Redox behavior and ionic conductivity of Al-doped Sr3LaFe3O10−δ
Materials Letters（2020）
Abstract
•Equilibrium p(O2)-T-δ diagrams of layered Sr3LaFe3−xAlxO10−δ were studied.•Statistical thermodynamic model was proposed and validated.•Thermodynamic parameters governing oxygen intercalation were calculated.•Charge-carrier concentrations and partial conductivities were determined.
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Key words
Layered ferrites,Defects,Simulation and modelling,Coulometric titration,Electrical properties,Ceramics
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