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SYNTHESIS OF GARUGAMBLIN-2, A MACROCYCLIC DIARYLHEPTANOID CONSTITUENT OF GARUGA-GAMBLEI

GM KESERU,M NOGRADI,M KAJTARPEREDY

LIEBIGS ANNALEN DER CHEMIE（1994）

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Abstract
The macrocyclic diarylheptanoid garugamblin-2 (1) and its constitutional and sterical isomers 17-19 were synthesized using the isoxazole derivative 8 for the introduction of the beta-methoxyenone function. Ring closure was accomplished by an intramolecular Wittig reaction.
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GARUGAMBLIN-2,DIARYLHEPTANOIDS,MACROCYCLES,GARUGA-GAMBLEI,CALCULATIONS, MMX, PM3
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