SYNTHESIS OF GARUGAMBLIN-2, A MACROCYCLIC DIARYLHEPTANOID CONSTITUENT OF GARUGA-GAMBLEI
LIEBIGS ANNALEN DER CHEMIE(1994)
Abstract
The macrocyclic diarylheptanoid garugamblin-2 (1) and its constitutional and sterical isomers 17-19 were synthesized using the isoxazole derivative 8 for the introduction of the beta-methoxyenone function. Ring closure was accomplished by an intramolecular Wittig reaction.
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Key words
GARUGAMBLIN-2,DIARYLHEPTANOIDS,MACROCYCLES,GARUGA-GAMBLEI,CALCULATIONS, MMX, PM3
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