PRINS REACTION USING TRIOXANE FOR TRISUBSTITUTED,& IT; cis & IT;-FUSED HEXAHYDRO-2 & IT;H & IT;-FURO[3,2-& IT;b & IT;]PYRAN DERIVATIVE

Oriel Hlokoane, Hiyori Itagaki,Manami Chiba,Taiki Noda,Yuichi Takasaki,Kei Miyako,Ryuichi Sakai,Yuichi Ishikawa,Masato Oikawa

HETEROCYCLES（2018）

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摘要

The construction of cis-fused heterobicyclic system involved in neuroactive natural products such as dysiherbaine has been accomplished by employing Prins strategy using 1,3,5-trioxane as an equivalent for formaldehyde. The reactions allowed stereoselective construction of the trisubstituted cis-fused hexahydro-2H-furo[3,2-b]pyran with maximum yield of 60%.

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