吡蚜酮镍及铜配合物的合成、晶体结构与电催化性能研究
CHINESE JOURNAL OF INORGANIC CHEMISTRY(2014)
Abstract
以吡蚜酮为配体合成了单核的镍配合物[Ni(L)2(Ac)2(H2O)2]·4H2O (1)和双核的铜配合物[Cu2(L)2(Ac)4]·2H2O(2)(L=吡蚜酮),并对化合物进行了元素分析、红外、热重、X射线衍射、循环伏安等分析.X-射线单晶衍射仪分析表明:化合物1属于三斜晶系,P-1空间群,镍离子采用六配位的变形八面体几何构型.化合物2属于单斜晶系,P21/c空间群,两个醋酸根桥连相邻的Cu(Ⅱ)离子形成了双核结构.电催化实验发现化合物1和2对H2O2具有明显的电催化活性.
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Key words
pymetrozine,nickel complex,copper complex,crystal structure,electrocatalysis
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