Stereoselective Total Synthesis of (-)-6-epi-Hygrophorone B-14 and (-)-4-epi-Hygrophorone D-14

Banothu Surender,Allam Vinaykumar,Bejugam Santhosh Kumar,Sahithya Phani Babu Vemulapalli,Batchu Venkateswara Rao

CHEMISTRYSELECT（2018）

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摘要

Total synthesis of (-)-6-epi-hygrophorones B-14 and (-)-4-epi-hygrophorone D-14 was achieved using stereoselective Grignard reaction, Bernet-Vasella protocol and Ring closing metathesis, starting from D-mannose.

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关键词

Hygrophorone,Oxidation,Ring Closing Metathesis,Stereoselective Grignard reaction,Vinylation

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