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A New Approach to the Synthesis of meso-CN-Substituted BODIPYs

Viktor P. Yakubovskyi,Natalia O. Didukh,Yuriy V. Zatsikha,Yuriy P. Kovtun

CHEMISTRYSELECT（2016）

Cited 18|Views4
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Abstract
A preparative synthetic procedure to the meso-CN substituted BODIPY has been developed. This method is based on the addition of KCN to the borondipyrromethene moiety of the meso-unsubstituted molecules in the presence of a crown ether with further oxidation with Pb(OAc)(4). The CN group at this position causes an essential bathochromic shift in absorption/emission and influence on other physicochemical properties of borondipyrromethenes over a wide range.
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Key words
BODIPY,Dyes,UV/vis spectroscopy,Fluorophores
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