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One-Pot, Solvent-Free Allylation or Propargylation of Carbonyl Compounds Mediated by the in situ Generated Zn-Ag Couple

Changquan Yu,Jian Yang, Lingjie Xia,Xiuyang Lu

ASIAN JOURNAL OF CHEMISTRY（2012）

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Abstract
Zn-Ag couple which was in situ generated by zinc being oxidized with catalytic silver acetate was successfully applied to the one-pot and solvent-free allylation or propargylation of carbonyl compounds, in which high yields, regioselective addition, waste minimization and simple operation can be achieved.
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Key words
Allylation,Propargylation,Zn-Ag couple,One-pot,Solvent-free
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