NEW N-N BOND-CLEAVAGE OF FUSED CHLOROPYRIDAZINES WITH YNAMINES
CHEMICAL & PHARMACEUTICAL BULLETIN(1994)
Abstract
1-Chlorophthalazine (1) reacts with a 2-fold molar excess of ynamines 2a, b to give penta-substituted pyridine derivatives 3a,b by nitrogen-nitrogen bond cleavage of the pyridazine ring with release of hydrogen chloride. Similarly, other fused pyridazines having a chloro substituent a to nitrogen in the pyridazine ring, i.e., pyrido[3,4-d]-(10a), pyrido[2,3-d]-(10b), thiazolo[4,5-d]-(10c,d), furo[2,3-d]-(10e) and pyrrolo[2,3-d]-(10f,g) pyridazine derivatives, gave the corresponding penta-substituted pyridines 11a-11k.
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Key words
PHTHALAZINE,BOND CLEAVAGE,YNAMINE,CONDENSED PYRIDAZINE
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