Revealing Defect-Induced Spin Disorder In Nanocrystalline Ni

We combine magnetometry and magnetic small-angle neutron scattering to study the influence of the microstructure on the macroscopic magnetic properties of a nanocrystalline Ni bulk sample, which was prepared by straining via high-pressure torsion (HPT). As seen by magnetometry, the mechanical deformation leads to a significant increase of the coercivity compared with nondeformed polycrystalline Ni. The neutron data reveal a significant spin-misalignment scattering caused by the high density of crystal defects inside the sample, which were created by the severe plastic deformation during the sample preparation. The corresponding magnetic correlation length, which characterizes the spatial magnetization fluctuations in real space, indicates an average defect size of 11 nm, which is smaller than the average crystallite size of 60 nm. In the remanent state, the strain fields around the defects cause spin disorder in the surrounding ferromagnetic bulk, with a penetration depth of similar to 22 nm. The range and amplitude of the disorder is systematically suppressed by an increasing external magnetic field. Our findings are supported and illustrated by micromagnetic simulations, which for the case of nonmagnetic defects (holes) embedded in a ferromagnetic Ni phase, further highlight the role of localized spin perturbations for the magnetic microstructure of defect-rich magnets such as HPT materials.