Directed synthesis of fluorine containing 2,3-dihydrobenzo[b][1,4]oxathiine derivatives from polyfluoroarenes

Journal of Fluorine Chemistry（2020）

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摘要

•General approach to the production of fluorinated 2,3-dihydrobenzo[b][1,4]oxathiine derivatives.•Structural modification of polyfluorinated benzoheterocycles via SNAr-reaction.•Synthesis of biologically important S,O-heterocyclic scaffolds in high yields.

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关键词

Polyfluorinated 2,3-dihydrobenzo[b][1,4]oxathiines,Aromatic nucleophilic substitution,Fluorinated S,O-heterocycles,Polyfluorinated 2-(vinylthio)phenol

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