The synthesis of 3-azabicyclo[4.3.0]nonane scaffolds from brefeldin A
Tetrahedron Letters(2020)
摘要
•Large scale fermentations of Penicillium camberti generated multi-kg quantities of brefeldin.•A triazoline derived from brefeldin serves as a useful building block for di-and tri-cyclic scaffolds.•New brefeldin derivatives were generated facilitated by microwave induced N2 expulsion and ring expansion.
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关键词
Brefeldin fermentation product,Natural products,Synthetic modification,Triazoline cyclization product
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