The influence of electronegativity on linear and triangular three-centre bonds
ARKIVOC（2020）
Abstract
Electronegativity differences between bonding atoms have major effects on the strengths of chemical bonds but they affect two-centre and three-centre bonds in different ways and with different consequences. The effect on two-centre bonds was recognised almost 100 years ago but the influence of electronegativity difference on three-centre bonding has received less attention. Molecular orbital models of three-centre bonding are discussed and their application to the understanding of the properties of three-centre bonded species illustrated. [GRAPHICS] .
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Key words
Three-centre bonding,electronegativity,hypervalent,nonclassical carbocations,2-norbornyl cation,xenon difluoride
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