Novel graphitic sheets with ripple-like folds as NCA-cathode coating layer for high-energy-density lithium-ion batteries.

In this work, novel graphitic sheets with ripple-like folds (GSRF) are synthesized from cheap resin via a facile route. The obtained GSRF are used as cladding layer for LiNi0.8Co0.15Al0.05O2 (NCA) particles to construct GSRF@NCA composite cathode. Electrochemical testing for GSFR@NCA exhibits better cycling and C-rate performance than those of original NCA. Moreover, the capacity retention (85%) of the full cell (GSFR@NCA vs. graphite) is much higher than that (79%) of the full cell (NCA vs. graphite) after 400 cycles. Most importantly, this approach allows the preparation of GSFR@NCA with highly promising applications as cathode for high-energy-density lithium-ion batteries, since in this contribution just simple equipment and precursor with low cost are involved.