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Recyclable Perovskite As Heterogeneous Photocatalyst for Aminomethylation of Imidazo‐Fused Heterocycles

Advanced synthesis & catalysis(2020)

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摘要
A sustainable and cost-effective protocol for direct aminomethylation of imidazo-fused heterocycles by decarboxylative coupling reaction of N-phenylglycines with imidazo-fused heterocycles in the presence of CsPbBr3 under the irradiation of visible light has been developed. This is the first example of CsPbBr3-catalyzed aminomethylation of imidazo-fused heterocycles. The eminent advantage of this work is in that, CsPbBr3 is easily prepared and can be used at least 5 times without obvious reduction in its activity, exhibiting high catalyst economic feature.
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关键词
Perovskites,Photocatalysis,Decarboxylative coupling,Heterogeneous catalysis
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