Dibenzocycloheptatriene As End-Group Of Thiele And Tetrabenzo-Chichibabin Hydrocarbons
CHEMICAL COMMUNICATIONS(2020)
摘要
Thiele (Th) and tetrabenzo-Chichibabin (TBC) derivatives with terminal dibenzocycloheptatriene (DBHept) units were prepared. A clear correlation between their electronic and molecular structures was stablished. Insights into their closed- or open-shell ground states were gained, where particular contribution of the heptagonal carbocycles as end-groups was proved. Remarkably, a thermally accessible triplet diradical configuration was confirmed for theDBHept-TBCcompound.
更多查看译文
关键词
hydrocarbons,thiele,end-group,tetrabenzo-chichibabin
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要