PtCl 2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso -fused β-β' dimer and its monomer analogue.
Chemical communications (Cambridge, England)(2020)
摘要
An unprecedented formation of a meso-fused β-β' carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl2 salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores.
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