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Assembly Of Polysubstituted Chiral Cyclopropylaminesviahighly Enantioselective Cu-Catalyzed Three-Component Cyclopropene Alkenylamination

Yu Zhang,Yuan Li,Wei Zhou,Mengru Zhang,Qian Zhang,Ran Jia,Jinbo Zhao

CHEMICAL COMMUNICATIONS（2020）

Cited 7|Views6
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Abstract
Enabled by a commercial bisphosphine ligand, the Cu-catalyzed three-component cyclopropene alkenylamination with alkenyl organoboron reagent and hyroxyamine esters proceeds with exceptionally high enantioselectivity to deliver poly-substitutedcis-1,2-alkenylcyclopropylamines that contain up to all three stereogenic centers on the cyclopropane.
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Key words
chiral,enantioselective,cu-catalyzed,three-component
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