Grain Growth Kinetics of 0.65Ca 0.61 La 0.26 TiO 3 -0.35Sm(Mg 0.5 Ti 0.5 )O 3 Dielectric Ceramic.

MATERIALS(2020)

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摘要
The 0.65Ca(0.61)La(0.26)TiO(3)-0.35Sm(Mg0.5Ti0.5)O-3[0.65CLT-0.35SMT] ceramic was prepared by the solid-state reaction method. The effects of sintering process on its microstructure and grain growth behavior were investigated. The Hillert model and a simplified Sellars model were established by linear regression, and the Sellars-Anelli model with a time index was established by using a nonlinear regression method. The results show that the grain size gradually increases with the increase of sintering temperature and holding time. Meanwhile, the sintering temperature has a more significant effect on the grain growth. The grain sizes of 0.65CLT-0.35SMT ceramic were predicted by the three models and compared with the experimentally measured grain size. The results indicate that for the 0.65CLT-0.35SMT ceramic, the Hillert model has the lowest prediction accuracy and the Sellars-Anelli model, the highest prediction accuracy. In this work, the Sellars-Anelli model can effectively predict the grain growth process of 0.65CLT-0.35SMT ceramic.
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关键词
CLT-SMT ceramic,growth models,nonlinear regression,dielectric materials
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