Iron(III)-Mediated Rapid Radical-Type Three-Component Deuteration of Quinoxalinones With Olefins and NaBD4.

Wanmei Li,Heng Cai,Lin Huang,Lei He,Yilan Zhang,Jun Xu, Pengfei Zhang

Frontiers in chemistry（2020）

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摘要

Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones. In this transformation, a radical pathway is involved according to the results of control experiments.

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