Hexanuclear Zn(Ii)-Induced Dense Pi-Stacking In A Metal-Organic Framework Featuring Long-Lasting Room Temperature Phosphorescence

A new strategy to enhance the room temperature phosphorescence performance has been developed through hexanuclear Zn(II)-cluster-induced dense pi-stacking in a metal-organic framework matrix. The synergistic effect of metal clusters and large overlap of pi-conjugated dimers facilitate the phosphorescence emission, migration, and separation of charge carriers for excellent photocatalytic activity.