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熵驱大分子胶体粒子的柱状受限结晶

Cuiling HOU,Guolong ZHU,Xiaobin DAI,Ziyang XU, Pengyu CHEN,Xuanyu ZHANG,Lijuan GAO,Litang YAN

高等学校化学学报（2020）

Cited 4|Views33
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Abstract
熵是物理化学的基本状态参量,在统计力学和热力学中处于核心位置. 按照玻尔兹曼的微观解释,熵可以由孤立系统微观状态的数目( W)给出,即S=kB lnW,这里kB为玻尔兹曼常数[1,2] . 根据此公式,微观状态数越多,系统越混乱,熵越大,所以熵常被视作体系无序程度的度量. 但熵增仅对应体系微观状态数的增加,与可观测的结构有序程度无关[3～5] .
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Key words
Entropic ordering,Colloid crystal,Order transition,Cylindrical confinement,Computational modeling
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