Lawrence Berkeley National Laboratory Recent Work Title Calcium isotope systematics at hydrothermal conditions : Mid-ocean ridge vent fluids and experiments in the CaSO 4-NaCl-H 2 O system Permalink

Two sets of hydrothermal experiments were performed to explore Ca isotope fractionation and exchange rates at hydrothermal conditions (410–450 C, 31.0–50.0 MPa). The first set of experiments determined the magnitude of vaporliquid Ca isotope fractionation and anhydrite solubility in the CaSO4-NaCl-H2O system. The data indicate no statistical difference between the Ca isotopic composition of coexisting vapor and liquid. The second set of experiments utilized an anomalous Ca spike to determine the rate of Ca exchange between fluid and anhydrite as a function of total dissolved Ca concentration. Results show that the rate of exchange increases with dissolved Ca concentrations (12–23 mM/kg), but no change in exchange rate is observed when the Ca concentration increases from 23 to 44 mM/kg Ca. 74–142 days are required to achieve 90% anhydrite-fluid Ca isotope exchange at the conditions investigated, while only several hours are necessary for vapor-liquid isotopic equilibrium. The lack of vapor-liquid Ca isotope fractionation in our experiments is consistent with dCa of mid-ocean ridge hydrothermal vent fluids that remain constant, regardless of chlorinity. Moreover, the narrow range of end member fluid dCa, 0.98 to 1.13‰ (SW), is largely indistinguishable from MORB dCa, suggesting that neither phase separation nor fluid-rock interactions at depth significantly fractionate Ca isotopes in modern high-temperature midocean ridge hydrothermal systems. 2018 Elsevier Ltd. All rights reserved.