Rsc_cc_c1cc12782a 1..3

Nieves Corella-Ochoa,Haralampos N. Miras,Alastair Kidd,De-Liang Long,Leroy Cronin

semanticscholar（2011）

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Abstract

The influence of the pyramidal heteroanion, TeO3 2 in the selfassembly of mixed metal (Mo/V) systems, is demonstrated by the isolation of three novel mixed-metal, mixed-valence architectures, {Mo12V12Te3} (1), {Mo12V12Te2} (2) and {Mo17V8Te} (3) with the tellurium centres exhibiting the novel l8-TeO4 and l9-TeO3 coordination modes while compounds 1 and 2 were discovered utilizing ESI mass spectrometry.

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