:H Films and Their Application to Amorphous Silicon Solar Cells

Optimization of p-type hydrogenated microcrystalline silicon oxide thin films (p-μc-Si 1−x O x :H) by very high frequency plasma enhanced chemical vapor deposition 40MHz method for use as a p-layer of a-Si:H solar cells was performed. The properties of p-μc-Si 1−x O x :H films were characterized by conductivity, Raman scattering spectroscopy, and spectroscopic ellipsometry.Thewide optical band gap p-μc-Si 1−x O x :H films were optimized by CO 2 /SiH 4 ratio and H 2 /SiH 4 dilution. Besides, the effects of wide-gap p-μc-Si 1−x O x :H layer on the performance of a-Si:H solar cells with various optical band gaps of p-layer were also investigated. Furthermore, improvements of open circuit voltage, short circuit current, and performance of the solar cells by using the effective wide-gap p-μc-Si 1−x O x :H were observed in this study. These results indicate that wide-gap p-μc-Si 1−x O x :H is promising to use as window layer in a-Si:H solar cells.