Reticular Growth of Graphene Nanoribbon 2D Covalent Organic Frameworks

Gregory Veber,Christian S. Diercks,Cameron Rogers,Wade S. Perkins,Jim Ciston,Alex Liebman-Peláez,Chenhui Zhu,Felix R. Fischer

semanticscholar（2019）

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摘要

Synthesis and characterization covalent organic frameworks (COFs) from a small molecule diamine and polydisperse cove type GNRs (c-GNRs) functionalized with aldehydes. The cGNR-COF films were found to contain crystalline regions (>100 nm2) of imine linked GNRs that could be chemically exfoliated into bilayer/trilayers utilizing a sonication protocol with o-dichlorobenzene (o-DCB).

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