Synthesis, structure and magnetism of a new ionic pentanuclear iron cluster
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY（2020）
Abstract
A new ionic pentanuclear Fe-III cluster, namely, triethylazanium tetrakis(mu(2)-5-amino-1,2,3,4-tetrazolido)tetrakis(mu(3)-4-chloro-2-{[(1H-tetrazol-1-id-5-yl)imino]- methyl}phenolato)di-mu(3)-oxido-pentairon(III) acetonitrile monosolvate monohydrate, (C6H16N)[Fe-5(C8H4ClN5O)(4)(CH2N5)(4)O-2]center dot CH3CN center dot H2O, was synthesized using microvial synthesis methods and characterized by elemental analysis, FT-IR spectroscopy, single-crystal X-ray diffraction and thermogravimetric analysis. Magnetic studies reveal that the complex displays dominant anti-ferromagnetic intracluster interactions between the Fe-III ions through the mu(3)-oxide bridges.
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Key words
pentanuclear cluster,iron(III),oxide,magnetic properties,antiferromagnetic,crystal structure
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