Axial Elongation of Mononuclear Lanthanide Metallocenophanes: Magnetic Properties of Dysprosium- and Terbium-[1]ruthenocenophane Complexes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2020)
摘要
We report the first f-block-ruthenocenophane complexes 1 (Dy) and 2 (Tb) and provide a comparative discussion of their magnetic structure with respect to earlier reported ferrocenophane analogues. While axial elongation of the rare trigonal-prismatic geometry stabilizes the magnetic ground state in the case of Dy3+ and results in a larger barrier to magnetization reversal (U), a decrease in U is observed for the case of Tb3+.
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关键词
f-block chemistry,inorganic,magnetization dynamics,organometallic,single-molecule magnet
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