Nanoscale metamaterials: Meta-MOFs and framework materials with anomalous behavior
Coordination Chemistry Reviews(2019)
Abstract
•Materials with abnormal physical or chemical properties are numerous among metal-organic frameworks and framework materials.•Unusual responses to stimulation range from counter-intuitive to thermodynamically forbidden.•Stimuli-responsive MOFs share large similarities with metamaterials.•These meta-MOFs have properties that go beyond the boundaries of common crystalline materials.
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Key words
Metal-organic frameworks,Framework materials,Metamaterials,Adsorption,Mechanical properties,Thermal expansion
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