Biocatalytic allylic hydroxylation of unsaturated triterpenes and steroids by Bacillus megaterium CGMCC 1.1741.

Wei Wang,Weiwei Wang,Haixia Ge,Guolong Li,Pingping Shen,Shaohua Xu,Boyang Yu,Jian Zhang

Bioorganic Chemistry（2020）

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摘要

•A new method to catalyze allylic hydroxylation of natural terpenes was provided.•Enzymes in Bacillus megaterium CGMCC 1.1741 deserve further exploration.•Fourteen unique derivatives of steroids and pentacyclic triterpenes were synthesized.

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关键词

Biotransformation,Allylic oxidation,Bacillus megaterium,Pentacyclic triterpenes,Δ5-steroids

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