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Pulchrol和Pulchral的合成研究

Dongdong Guo,,Wuxia Zhang,,Wenmei Gao,,Xiaodi Guo,,Yongqiang Wang,

CHINESE JOURNAL OF ORGANIC CHEMISTRY（2019）

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Abstract
以廉价的对苯二酚和4-甲基苯甲酸为原料,以钯催化芳烃羧酸与芳基溴化物的分子内脱羧偶联为关键反应,合成了具有抗疟原虫活性的天然产物pulchrol和pulchral,总收率分别为14％和11％.该合成为进一步研究构效关系提供了基础.
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Key words
natural product,total synthesis,cross-coupling,pulchrol,pulchral
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