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Versatile synthesis of cadalene and iso-cadalene from himachalene mixtures: Evidence and application of unprecedented rearrangements

Mustapha Ait El Had,Abdelouahd Oukhrib,Mohamed Zaki,Martine Urrutigoïty,Ahmed Benharref,Remi Chauvin

Chinese Chemical Letters（2020）

Cited 3|Views8
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Abstract
A versatile selective valorization of an abundant essential oil mixture from Atlas cedar is disclosed: it relies on unprecedented redox-controlled skeletal rearrangements in aromatic chemistry, occurring under green conditions.
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Key words
Aromatic reactivity,Cadalenes,Dihydrocurcumene,Himachalenes,Rearrangements
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