Enantioselective formal synthesis of the marine macrolide (-)-callyspongiolide.

Aina Urbina,Núria Llor,Maria Vittoria Barbieri,Joan Bosch,Mercedes Amat

CHEMICAL COMMUNICATIONS（2020）

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摘要

A short enantioselective synthesis of the macrocyclic core 19 of callyspongiolide, involving a homocrotylboration of aldehyde 4, a Still-Genari olefination, an esterification with alcohol 17, and a ring-closing metathesis, is reported.

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enantioselective formal synthesis,marine macrolide

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