Well-constructed Ni@CN material derived from di-ligands Ni-MOF to catalyze mild hydrogenation of nitroarenes

Haijun Pan, Yuanyuan Peng,Xinhuan Lu,Jie He,Lin He,Chenlong Wang,Fanfan Yue,Haifu Zhang,Dan Zhou,Qinghua Xia

Molecular Catalysis（2020）

引用 51|浏览14

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摘要

The hydrogenation of nitrobenzene to aniline has been effectively carried out over Ni@CN-x catalysts. The results show that Ni@CN-500 composite catalyst exhibits an excellent performance to achieve 99.1 mol% conversion of nitrobenzene and >99 % selectivity of aniline under reaction conditions of 2.0 MPa H2 and 60 °C.

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关键词

Ni-MOFs,Ni@CN,Selective hydrogenation,Nitroarenes,Mild conditions

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