Review of heterogeneous methanol carbonylation to acetyl species
Applied Catalysis A: General(2020)
摘要
•An insightful review on heterogeneous methanol carbonylation with mechanism.•The emphasis on coordinationally or ionically supported new Rh carbonylation centers.•The thoroughly studied Ir-La/C system with a different center from homogeneous one.•The emphasis on combination with “single-site” and “ionically bound mode”.•Iodine-free and green zeolites suffer from low activity and two-step process.
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关键词
Heterogeneous methanol carbonylation,Single-site,Supported metal catalyst,Rh catalyst,Ir catalyst
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