Paleo-environmental variation and its control on organic matter enrichment of black shales from shallow shelf to slope regions on the Upper Yangtze Platform during Cambrian Stage 3

To understand the evolution of oceanic redox conditions and organic matter (OM) accumulation in the shelf and slope regions of the Upper Yangtze Platform during Cambrian Stage 3, high-resolution geochemical data were obtained from two wells respectively representing shelf and slope environments. Based on redox proxies, widespread anoxic/euxinic waters with intermittent sulfidic water columns were formed from shallow shelf to deep water slope and basinal regions during Stage 2 and early Stage 3; then, widespread anoxic waters were reduced and oxic waters expanded during the middle Stage 3, after which fluctuating suboxic and oxic (occasionally anoxic) environments became predominant during late Stage 3. The presence of hyalophane and positive Eu anomalies suggest strong Ba-rich hydrothermal activities in the shelf and deep basin regions during early and middle Stage 3. The Ba-rich hydrothermal fluids and upwelling events enhanced the primary productivity in surface waters and subsequently promoted organic matter enrichment. During Stage 2 and early Stage 3, the high primary productivity driven by coastal upwelling and hydrothermal activity were the main factors controlling OM enrichment; during middle Stage 3, the local anoxic water condition became responsible for OM enrichment when oxic waters began to gradually expand; during late Stage 3, both primary productivity and redox conditions became the main control factors for OM enrichment. According to the analysis of primary productivity, redox conditions, hydrothermal activity and upwelling events, an evolution model is proposed to account for the paleo-environmental variation and the OM enrichment from shallow shelf to slope regions during Cambrian Stage 3.