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Interaction between 2-pyrrolidine-1-hydroxymethane-1,1-diphosphonic acid and palladium(II) in aqueous solutions

O.M. Kozachkova,N.V. Tsaryk, O.O. Shtokvish,V.I. Pekhnyo,V.V. Trachevskii,A.B. Rozhenko,V.V. Dyakonenko

Inorganica Chimica Acta（2020）

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Abstract
Acid–base properties of 2-pyrrolidine-1-hydroxymethane-1,1-diphosphonic acid were studied. Its structure was evaluated by single-crystal X-ray diffraction. Complexation of K2[PdCl4] with 2-pyrrolidine-1-hydroxymethane-1,1-diphosphonic acid was studied by pH-potentiometry, UV–Vis, as well as by 31P, 13C and 1H NMR spectroscopy.
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Key words
Diphosphonic acid,Complexes of palladium(II),Formation constants,UV–Vis,NMR spectroscopy,X-ray diffraction
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