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Aromatic substituent effects in palladium-catalyzed intramolecular olefin oxyarylation reactions

Mark C. Maust,Zacary L. Croft,Mackenzie W. Sullivan, Ross L. Dove,Emily E. Hardy,W.E. Brenzovich

Tetrahedron Letters（2020）

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Abstract
•Palladium-catalyzed oxyarylation can be accomplished in an intramolecular fashion.•High oxidation-state palladium catalysis can initiate an aryl rearrangements.•The regiochemistry of aryl addition is highly dependent on electron-donating groups.
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Key words
Palladium,Olefin difunctionalization,Oxidative,Cyclization
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