2,6-Pyridinedicarbohydrazide-Salicylal hydrazone-base derivative with High detection limit and binding Constant for emissive ion chemosensing in aqueous solution
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY(2020)
Abstract
A new tridentate luminescent molecule, N-2,N-6-bis(salicylidene)pyridine-2,6-dicarbohydrazide (BSPDH), was introduced and facilely eco-synthesized with high yield. It was then characterized through Fourier transform infrared, Hydrogen-1 nuclear magnetic resonance, Carbon-13 nuclear magnetic resonance, mass and photoluminescence spectroscopy, X-Ray Diffraction and Ultraviolet-visible absorption methods. BSPDH showed an enhanced aggregation-induced emission as well as highly fast-response "turn-off" selectivity and sensitivity behaviors towards Cu2+ ions in aqueous solutions at physiological pH. Density Functional Theory calculations confirmed the formation of strong BSPDH-Cu2+ complex with lower energy gap compared to BSPDH. Among PDH-base fluorescent sensors reported so far, BSPDH is the first tautomerization-base luminescence molecular chemo-sensor with the high detection limit of 3.11 x 10(-5) M and binding constant of 1.978 x 10(5) M-1 at the concentration of 10 mu M of BSPDH for detecting Cu2+ ions without any interference from other metal cations in the aqueous solution at the physiological pH.
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Key words
Molecular fluorescent chemo-sensor,Salicylaldehyde derivative,AIEE-activity,Diacylhydrazone,Tridentate ligand
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