Enhancing easy-plane anisotropy in bespoke Ni(II) quantum magnets

Jamie L. Manson,Zachary E. Manson,Ashley Sargent,Danielle Y. Villa, Nicole L. Etten,William J.A. Blackmore,Samuel P.M. Curley,Robert C. Williams,Jamie Brambleby,Paul A. Goddard,Andrew Ozarowski,Murray N. Wilson,Benjamin M. Huddart,Tom Lancaster,Roger D. Johnson,Stephen J. Blundell,Jesper Bendix,Kraig A. Wheeler,Saul H. Lapidus,Fan Xiao

Polyhedron（2020）

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摘要

By design, targeted pseudo-octahedral Ni(II) complexes composed of simple ligands L show easy-plane anisotropy with 8 ≤ D ≤ 25 K. For small donor-atoms; e.g., N, F, and O, D is the largest for NiN4F2 and smallest for NiN4O2. This correlates with Ni-Lax ≤ Ni-Neq and the ligand spectro-chemical properties.

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关键词

Quantum magnetism,Anisotropy,Low-dimensional,High magnetic fields,Nickel

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